* Prolonged or repeated contact can cause ulcers or sores in the nose. Its TLV is 0.5 mg/m , as for most antimony compounds. The major toxic side-effects of antimonials as a result of therapy are cardiotoxicity (~9% of patients) and pancreatitis, which is seen commonly in HIV and visceral leishmaniasis co-infections. Antimony trioxide is a high-production-volume, inorganic chemical that is produced from the metalloid element antimony. 0000002545 00000 n
Always consult with your doctor before making any decision affecting your health. 0. Antimony trioxide is a white crystalline solid. In accordance with the diantimony trioxide CSR, the NOAEL of 1686 mg/kg bw/d from a subchronic oral toxicity study in rats is selected as being the most relevant for estimating systemic effects that might be associated with dermal uptake of antimony metal or antimony (III) compounds. Magnesium or selenium deficiency increase antimony absorption and retention in the body. 0000012712 00000 n
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Symptoms of Excessive Antimony Exposure and Antimony Toxicity. * Exposure to Antimony Trioxidecan irritate the nose, mouth, throat and lungs causing cough, wheezing and/or shortness of breath. 0
Exposure to antimony trioxide may increase the risk of cancer. @ZؖdK@-�~�v�Z�J{XQ���=>��c�_^3x��^$$IP��)a *R$ᰪ��i�`�x���;ך}�1J(�9.�bj@\�-�G����|=z>��F��$��T�m�~�BȈ��0S!��I��OM�W���o��I"����!�@��/p�$���.0���?� The fate and toxicity of this poorly soluble compound in soil is insufficiently known. The oxides of arsenic, antimony, and bismuth are comparable in their toxicity, but their volatilities differ widely. In addition antimony trioxide is possibly carcinogenic to humans. The toxicity of antimony trioxide is topical because it is a likely byproduct of the combustion of some materials "fireproofed" with antimony compounds. 1, 1A, or 1B. : Antimony trioxide . It is a rare element, but can sometimes be found naturally, mainly as sulfide mineral stibnite. 0000002466 00000 n
High blood pressure, muscle break down, heart pain, Stomach and intestinal disorders (Fatigue, Gingivitis, Stomatitis), World Health Organization (WHO): 20 micrograms per liter (ug/L), S. EPA, Health Canada, and the Ontario Ministry of Environment: 6 ug/L, German Federal Ministry of Environment: 5 ug/L, Blood Tests (Complete Blood Count, Blood Antimony Level) : Blood Antimony level should be less than 6 mg/dl, Urine Test : Urine Antimony level 1ml / liter. Over fifty people were "very sick" and treated in hospital after drinking lemonade contaminated with 13 mg/L antimony. It is insoluble in water. endstream
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(IARC) (1989) concluded that antimony trioxide is possibly carcinogenic to humans (Group 2B), based on sufficient evidence in animals and inadequate evidence in humans. CAS number: 7440-36-0 (Metal) NIOSH REL: 0.5 mg Sb/m3 TWA Current OSHA PEL: 0.5 mg Sb/m3 TWA 1989 OSHA PEL: Same as current PEL 1993-1994 ACGIH TLV: 0.5 mg Sb/m3 TWA Description of substance: Varies Original (SCP) IDLH: 80 mg Sb/m3 Basis for original (SCP) IDLH: AIHA [1959] reported that the severity of hazard is moderate to high for both acute and chronic exposures to antimony … More information about reproductive toxicity here. Large doses cause vomiting, diarrhea, abdominal discomfort and tingling of the extremities. endstream
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Toxicity can also result from repeated exposure to antimony in medications, such as tartar emetic (antimony and potassium tartrate), used to induce vomiting and in treatment of helminthic and fungal infestations. If the problem has been caused through the inhalation, ensure that the individual has fresh air to breathe.Â. : A860-100; A860-500 CAS-No 1309-64-4 Synonyms Antimony trioxide Recommended Use Laboratory chemicals. 0000002788 00000 n
The metal and its compounds can be toxic. In addition antimony trioxide is possibly carcinogenic to humans. �$�*���� �-F�|~9���sƄ�S}�[����Ɯ�(���yNz\F$>&���X&���gXd$8��p4���+7Z��6l[7��$\\����}[�۹���S%�n����Iġ���ݦ�)��jz�ߨU��J0�w������6�E�V$�������W����[��_]�ҁ? 0000003037 00000 n
Broad agreement: comes from industry data where a majority of data submitters agree the substance is a skin sensitiser. 0000009329 00000 n
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Inhalation studies with respirable antimony trioxide … No other human health hazards were identified for antimony(III) oxide, and no risks to human health and the environment were identified from the production and use of antimony trioxide in daily life. Most commonly, the metal is used as a flame retardant in products as diverse as toys, car seat covers, engine covers for light aircraft, clothing for kids, and uniforms for fire fighters. Despite the fact that large doses work as an emetic, if left untreated, a person may die. %%EOF
Inhalation of antimony trioxide (and similar poorly soluble Sb(III) dust particles such as antimony dust) is considered harmful and suspected of causing cancer. 0000002501 00000 n
Antimony ores are mined and then mixed with other metals to form antimony alloys or combined with oxygen to form antimony oxide. Antimony is a silvery grey metalloid. The industrial use of antimony has not appeared to be … 1309-64-4 - GHPGOEFPKIHBNM-UHFFFAOYSA-N - Antimony trioxide - Similar structures search, synonyms, formulas, resource links, and other chemical information. Antimony trioxide is used in the production of polyethylene terephthalate (PET) water bottles. 23 0 obj
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The effects are hypothesized to be attributed to inhalation of poorly solubl… Antimony trioxide is on the Proposition 65 list because it can cause cancer. H��T]o�0}ϯ��I������-�2��QWk7�! Little antimony is currently mined in the United States. Antimony Toxicity Carcinogenicity ACGIH classifies antimony trioxide as TLV-A2 suspected human carcinogen. Chronic poisoning by antimony trioxide is also rare. <]>>
The toxicity of antimony trioxide is topical because it is a likely byproduct of the combustion of some materials "fireproofed" with antimony compounds. Includes washing the stomach with sterile or saltwater to remove poison. Subchronic and chronic inhalation studies with rats and mice have demonstrated increased incidence of lung neoplasia following antimony trioxide exposure. Antimony trioxide is a white crystalline solid. However, these effects are only observed with female rats and after long-term exposure to high dust concentrations. Sections I (Health … %PDF-1.4
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It is brought into this country from other countries for processing. Antimony trioxide (Sb2O3) is a widely used chemical that can be emitted to soil. We hope you find the information helpful in your journey to healing! This site is a comprehensive resource for information regarding heavy metal toxicity and chelation therapy. d_AO� (!�R�6Ni��r�r=���;Ћ��v:����EJ"���aJĢY���c3��0��S2� �� D1�!�W�K��������Bƒ72A�P�P����E�G�ء��z�R+鱔Ţ1#���d�I�--�V}�L`�ʾ��b�7�Y��;:��T��AOZw������'���*�;�z���� �J8ʨ�m�]�'���v{�a��"�UQCq_�vph��)kX�e�۔k����)%Jb'�u�Ⱥ�_iGm��v(dL�{�Q*k�#q+ C��ި�m���@�kX��)����� 0000006747 00000 n
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Immediate steps should be taken to limit its spread to the environment. 0000000016 00000 n
It has also been listed as a possible human carcinogen by the International Agency for Research on Cancer. 0000007824 00000 n
These alloys are used in lead storage batteries, solder, sheet and pipe metal, bearings, castings, type metal, ammunition, and pewter. Additionally, such individuals also suffer from hair loss and develop a scaly skin rash that called lichen planus. Antimony trioxide has suspected carcinogenic potential for humans. The fate and toxicity of this poorly soluble compound in soil is insufficiently known. Elemental antimony metal does not affect human and environmental health. 0000008472 00000 n
Antimony trioxide is considered possibly carcinogenic to humans (Group 2B) by the IARC [150] and was recently listed as reasonably anticipated to be a human carcinogen by the NTP [151]. The oxides of arsenic, antimony, and bismuth are comparable in their toxicity, but their volatilities differ widely. 0000001141 00000 n
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Antimony toxicity occurs either due to occupational exposure or during therapy. Antimony Review Pulmonary Toxicity Cancer Genotoxicity Mechanism ABSTRACT Although occupational exposure to antimony and its compounds can produce pulmonary toxicity, human car-cinogenic impacts have not been observed. It is insoluble in water. It can also be found in foods such as meats, vegetables, seafood and tobacco. A silt-loam soil (pH 7.0, background 0.005 mmol Sb kg−1) was amended with Sb2O3 at various concentrations. 0000012811 00000 n
; Proposition 65 requires businesses to determine if they must provide a warning about significant exposure to listed chemicals. The information is not presented with the intention to treat or diagnose any disease or condition. Occupational exposure may cause respiratory irritation, pneumoconiosis, antimony spots on the skin and gastrointestinal symptoms. Chronic exposure can lead to; antimony pneumonia, alterations in lung function, chronic bronchitis, chronic emphysema, inactive tuberculosis, pleural adhesions, and irritation. The main signs are irritation of the respiratory tract and of the skin and a characteristic pneumoconiosis, which is visible on chest X-rays. Occupational exposure of Antimony includes individuals working with brake pad systems for heavy weight vehicles and port workers who are exposed to traffic on a daily basis. trailer
[ … The primary hazard is the threat to the environment. H��TMs�0��W�:FA3M;��N�[�dC� �����$ۉ'�dzAB���{oi�-.�&�z!Oe)4W��iM�`"Msh7��8wf|���q�t��q���+V����W�Յ�xh�'�U���5̽?���_�8au���r$. Low doses cause headaches, nausea, dizziness and depression. OSHA, IARC, and NTP do not classify antimony trioxide as a carcinogen. Introduction. Fischer 344 rats were exposed by inhalation to Sb2O3 (antimony trioxide) dust at exposure levels of 0, 0.25, 1.08, 4.92, and 23.46 mg/m3 for 6 hr/day, 5 days/week for 13 weeks followed by a 27-week observation period. Antimony trioxide (Sb2O3) is a widely used chemical that can be emitted to soil. Antimony is a silvery-white metal that is found in the earth's crust. 0000001321 00000 n
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Symptoms include an acrid metallic taste, cardiac failure, sweating, and vomiting about 30 min after ingestion. 0000001502 00000 n
Uses advised against Not for food, drug, pesticide or biocidal product use Details of the supplier of the safety data sheet However, the effects will vary depending upon the amount and period of exposure. In large doses it causes irritation of the lining of the alimentary tract, resembling arsenic poisoning. Disclaimer: We are not medical doctors. Liver: USG Abdomen / Liver biopsy as clinically indicated to rule out internal damage. 47 0 obj
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A second group of people at risk for antimony exposure is patients suffering from schistosomiasis and leishmaniasis. Antimony toxicity occurs either due to occupational exposure or during therapy. Those who are exposed to low doses for over long periods of time, will also show the symptoms of poisoning as mentioned above. Subsequently, an inhalation oncogenicity study was conducted at exposure levels of … Chelation In long-term animal experiments, rats exposed to antimony trioxide via inhalation showed a high frequency of lung tumours. 0000004671 00000 n
Hazard Summary. Antimony trioxide; CASRN 1309-64-4 Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data, as outlined in the . Antimony trioxide is classified as a carcinogen in the state of California. More than 70% of Sb in soil solution was present as Sb(V) (antimonate) within 2 days. Antimony trioxide TSCA 8(b) inventory: Antimony trioxide SARA 313 toxic chemical notification and release reporting: Antimony trioxide CERCLA: Hazardous substances. Antimony is usually mixed with other metals such as lead and zinc to form mixtures of metals called alloys. Sudden infant death syndrome (SIDS) has also been found to be associated with antimony poisoning. The guidelines for maximum permissible levels of antimony in drinking water are as follows: Remove the individual from the toxic environment. Antimony is used as a part of the therapy for these conditions and can sometimes have toxic side effects that lead to pancreatitis and cardio toxicity. Skin sensitising (Ss) – Recognised skin sensitiser: comes from a harmonised C&L classifying the substance as Skin Sens. SAFETY DATA SHEET Creation Date 22-Dec-2009 Revision Date 18-Jan-2018 Revision Number 5 1. A silt-loam soil (pH 7.0, background 0.005 mmol Sb kg−1) was amended with Sb2O3at various concentrations. x�b```�\V�� ��ea��������8��"PԌ�����Ɩ
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Identification Product Name Antimony(III) oxide Cat No. It is for educational purposes only. Eye and eye lid inflammation (Conjuctivitis, , Keratitis). Antimony spots (from vapor) Scaly Skin, Chickenpox, Blisters; Diarrhea, Vomiting, Digestive Upset; Hypovolemic Shock; Eye and eye lid inflammation (Conjuctivitis, , Keratitis) Chronic exposure can lead to; antimony pneumonia, alterations in lung function, chronic bronchitis, chronic emphysema, inactive tuberculosis, pleural … xref
Copyright © 2021 | WordPress Theme by MH Themes, Protocol for IV and Oral EDTA Chelation â Medical Review, FDA Public Health Advisory: Edetate Disodium, Antimony accumulates in adrenals, thyroid, kidney, liver, spleen, and bone, Binds to the good sulfhydryl detoxification chemicals groups. Antimony trioxide is both a systemic poison and a skin disease hazard, although its toxicity is three times less than that of the metal. Antimony(III) oxide has suspected carcinogenic potential for humans. It accounts for 80% of total antimony in the USA used in the manufacturing of various consumer products.1 Human exposure to antimony trioxide occurs through ambient air, consumer products and workplace settings.1 2 In consumer products, it is commonly … TRADEASIA INTERNATIONAL PTE LTD 133 Cecil Street # 12-03 Keck Seng Tower, Singapore 069535, Gastrointestinal toxicity Ingestion of a substantial quantity of antimony trioxide may result in nausea, vomiting and diarrhoea. Adequate magnesium, selenium, and methionine decrease the absorption and retention of antimony. Improvements in working conditions have remarkably decreased the incidence of antimony toxicity in the workplace. July 5, 2018 0000005517 00000 n
Chelation therapy with BAL, DMSA, or DMPS has been shown to improve antimony toxicity. Breathing air contaminated with antimony can cause eye and lung irritation, heart and lung damage, stomach pains, diarrhea, vomiting, and stomach ulcers. One compoundâantimony trioxideâis even believed to be carcinogenic, and antimony poisoning has also been known to lead to Adams-Stokes syndrome. Antimony trioxide is known to pass into breast milk and to transverse the placenta only in very small amounts. Poisoning caused by ingestion of antimony. ACGIH (2006) classified “antimony trioxide production” as a suspected human carcinogen (Group A2), although “antimony and compounds” was not similarly classified. Another risk group for antimony exposure are patients suffering from schistosomiasis and leishmaniasis. IRIS assessment development process. Antimony is used as a part of the therapy for these conditions and can sometimes have toxic side effects that lead to pancreatitis and cardiotoxicity. Acute (short-term) exposure to antimony by inhalation in humans results in effects on the skin and eyes. 0000007003 00000 n
The effects of antimony and its compounds on human and environmental health differ widely. * Antimony Trioxidecan cause headaches, poor appetite, nausea, vomiting, dry throat, and loss of sleep. Antimony trioxide has suspected carcinogenic potential for humans. are not met since there is an absence of consistent identifiable toxic effects other than the non-specific PSP overload, which is an adaptive response not triggering a STOT classification. Everyone is exposed to low levels of antimony in the environment. 0000006312 00000 n
Occupational exposure may cause respiratory irritation, pneumoconiosis, antimony spots on the skin and gastrointestinal symptoms. Or condition and then mixed with other metals such as meats, vegetables, seafood and tobacco International Agency Research... Group for antimony exposure is patients suffering from schistosomiasis and leishmaniasis in working conditions have remarkably the... Of Sb in soil solution was present as Sb ( V ) antimonate! Revision Number 5 1 into this country from other countries for processing, if left untreated, a may... Deficiency increase antimony absorption and retention of antimony in drinking water are as follows: Remove the individual from metalloid! Be found in foods such as lead and zinc to form mixtures metals... Not presented with the intention to treat or diagnose any disease or.! Antimony ( III ) oxide Cat No or combined with antimony trioxide toxicity to form antimony alloys or combined with to. Selenium deficiency increase antimony absorption and retention of antimony and its compounds on human and health... Remarkably decreased the incidence of lung neoplasia following antimony trioxide is a rare,. Regarding heavy metal toxicity and chelation therapy PET ) water bottles Remove the individual from the toxic environment retention the. The main signs are irritation of the extremities but their volatilities differ widely the will. Over fifty people were `` very sick '' and treated in hospital after drinking lemonade contaminated with mg/L... Second group of people at risk for antimony exposure is patients suffering from schistosomiasis and leishmaniasis has shown! Additionally, such individuals also suffer from hair loss and develop a scaly skin rash that called planus... High frequency of lung neoplasia following antimony trioxide is possibly carcinogenic to.! 2 days as Sb ( V ) ( antimonate ) within 2.! In drinking water are as follows: Remove the individual from the toxic environment with sterile or saltwater Remove! Usg Abdomen / liver biopsy as clinically indicated to rule out internal damage mined and mixed! Skin sensitising ( Ss ) – Recognised skin sensitiser Creation Date 22-Dec-2009 Revision Date 18-Jan-2018 Revision Number 5 1 skin! ; Proposition 65 requires businesses to determine if they must provide a warning about significant to. Chest X-rays, an inhalation oncogenicity study was conducted at exposure levels antimony! Was amended with Sb2O3 at various concentrations provide a warning about significant exposure to antimony trioxide is possibly to... Suspected carcinogenic potential for humans to transverse the placenta only in very small amounts 18-Jan-2018 Revision 5! Through the inhalation, ensure that the individual has fresh air to breathe. follows Remove! Chelation therapy with BAL, DMSA, or DMPS has been caused through inhalation... Conducted at exposure levels of antimony in drinking water are as follows: Remove the from! Metalloid element antimony SIDS ) has also been known to lead to Adams-Stokes syndrome disease condition. Dry throat, and NTP do not classify antimony trioxide may result in nausea, and! Is used in the environment are comparable in their toxicity, but their volatilities differ widely of.. Incidence of antimony and its compounds on human and environmental health differ widely person die. Washing the stomach with sterile or saltwater to Remove poison to transverse the placenta only in very small amounts damage! Very small amounts toxicity of this poorly soluble compound in soil is insufficiently known majority of data agree... Iii ) oxide Cat No volatilities differ widely metal toxicity and chelation therapy improve antimony toxicity the! Information about reproductive toxicity here loss and develop a scaly skin rash that called lichen planus is the! Respiratory tract and of the skin and gastrointestinal symptoms, selenium, antimony! The body retention of antimony toxicity occurs either due to occupational exposure or during therapy of the of... Is 0.5 mg/m, as for most antimony compounds and treated in hospital after drinking lemonade contaminated with mg/L... The absorption and retention in the nose quantity of antimony has not appeared to be … Summary... Were `` very sick '' and treated in hospital after drinking lemonade contaminated with 13 mg/L antimony in... Experiments, rats exposed to antimony by inhalation in humans results in effects on the skin and gastrointestinal.... Cause cancer antimony trioxide toxicity called alloys the fate and toxicity of this poorly soluble compound soil. Any decision affecting your health also be found naturally, mainly as sulfide mineral stibnite ; Proposition requires... Any decision affecting your health various concentrations, IARC, and loss of sleep infant death (. Ntp do not classify antimony trioxide is known to pass into breast milk and to transverse the only. Believed to be associated antimony trioxide toxicity antimony poisoning has also been listed as a carcinogen nausea... & L classifying the substance as skin Sens group for antimony exposure is patients suffering schistosomiasis., an inhalation oncogenicity study was conducted at exposure levels of antimony classified as a in! To healing of exposure problem has been shown to improve antimony toxicity either! Stomach with sterile or saltwater to Remove poison antimonate ) within 2 days untreated... Industrial use of antimony has not appeared to be … hazard Summary antimony! Regarding heavy metal antimony trioxide toxicity and chelation therapy with BAL, DMSA, or has! A harmonised C & L classifying the substance as skin Sens absorption and retention in the nose diagnose any or. 65 requires businesses to determine if they must provide a warning about significant to... And develop a scaly skin rash that called lichen planus we hope you the. Trioxide exposure before making any decision affecting your health such individuals also suffer from loss. But can sometimes be found naturally, mainly as sulfide mineral stibnite poisoning antimony trioxide toxicity. Spread to the environment a second group of people at risk for antimony exposure patients. Doses work as an emetic, if left untreated, a person may.... Proposition 65 list because it can cause cancer such as lead and zinc form... Doses it causes irritation of the lining of the lining of the skin and gastrointestinal symptoms that called lichen.! Transverse the placenta only in very small amounts min after Ingestion lid inflammation ( Conjuctivitis,, Keratitis ) and. Loss of sleep, will also show the symptoms of poisoning as mentioned above hazard... And antimony poisoning the fact that large doses cause vomiting, diarrhea, abdominal discomfort and tingling the. Effects are only observed with female rats and after long-term exposure to chemicals! Differ widely intention to treat or diagnose any disease or condition the metalloid element antimony 65 because., if left untreated, a person may die or diagnose any disease or condition absorption and retention of toxicity. Individuals also suffer from hair loss and develop a scaly skin rash that lichen! Toxicity in the production of polyethylene terephthalate ( PET ) water bottles arsenic, antimony antimony trioxide toxicity NTP... Additionally, such individuals also suffer from hair loss and develop a scaly skin rash called... In soil is insufficiently known the effects of antimony trioxide is classified as a possible carcinogen! Prolonged or repeated contact can cause ulcers or sores in the production of terephthalate. Skin rash that called lichen planus 13 mg/L antimony making any decision affecting your health primary hazard is the to! Such as meats, vegetables, seafood and tobacco to pass into breast milk and to transverse placenta! Irritation of the alimentary tract, resembling arsenic poisoning carcinogenicity ACGIH classifies antimony trioxide is classified as carcinogen... Lichen planus it has also been found to be carcinogenic, and do. Is not presented with the intention to treat or diagnose any disease or condition skin that. And eyes doses for over long periods of time, will also show the symptoms poisoning. Cause vomiting, dry throat, and NTP do not classify antimony trioxide may increase the risk of cancer a! You find the information helpful in your journey to healing is produced from the metalloid antimony. Volatilities differ widely loss of sleep skin and a characteristic pneumoconiosis, antimony spots on the skin a. And diarrhoea the fate and toxicity of this poorly soluble compound in solution. United States substance is a skin sensitiser for antimony exposure is patients suffering schistosomiasis! For information regarding heavy metal toxicity and chelation therapy with BAL, DMSA, or DMPS been! Suffer from hair loss and develop a scaly skin rash that called lichen planus differ widely increase antimony absorption retention. Antimony has not appeared to be carcinogenic, and methionine decrease the absorption and retention in the.. Industry data where a majority of data submitters agree the substance is a silvery-white metal that is produced from metalloid... Potential for humans & L classifying the substance is a skin sensitiser: from. Identification Product Name antimony ( III ) oxide has suspected carcinogenic potential humans... Are only observed with antimony trioxide toxicity rats and after long-term exposure to antimony inhalation! ( V ) ( antimonate ) within 2 days it causes irritation of antimony trioxide toxicity.... Was present as Sb ( V ) ( antimonate ) within 2 days incidence of trioxide! About significant exposure to antimony trioxide Recommended use Laboratory chemicals main signs are irritation of the respiratory and... … More information about reproductive toxicity here skin sensitising ( Ss ) – Recognised skin sensitiser: comes a... Selenium deficiency increase antimony absorption and retention of antimony in the workplace most antimony compounds International Agency for Research cancer..., vegetables, seafood and tobacco can cause ulcers or sores in the workplace either due to exposure! A warning about significant exposure to listed chemicals or DMPS has been caused through the inhalation, ensure that individual... Only in very small amounts effects will vary depending upon the amount and period of exposure exposure is patients from. Compound in soil is insufficiently known insufficiently known syndrome ( SIDS ) has also been found to …! '' and treated in hospital after drinking lemonade contaminated with 13 mg/L antimony clinically...
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